The easiest way is to hold a pair of wires together and turn the stepper – if it’s hard to turn, that’s a pair, if not, try another pairing.
It doesn’t matter which wire goes where, as long as they are a matching pair connected to a matching A or B of ports.
425oz steppers are going to stretch a TinyG – keep an eye on the temperatures. Be prepared to purchase external drivers – they are cheap enough, nowadays.